Reactive Quenching Of Od A (2)Σ(+) By H-2: Translational Energy Distributions For H- And D-Atom Product Channels

The H- and D-atom products from collisional quenching of OD A (2)Sigma(+) by H-2 are characterized through Doppler spectroscopy using two-photon (2 S-2 \u3c-\u3c- 1 S-2) laser-induced fluorescence. Partial deuteration enables separation of the channel forming H + HOD products, which accounts for 75% of reactive quenching events, from the D + H2O product channel. The Doppler profiles, along with those reported previously for other isotopic variants, are transformed into product translational energy distributions using a robust fitting procedure based on discrete velocity basis functions. The product translational energy distribution for the H- atom channel is strongly peaked at low energy (below 0.5 eV) with a long tail extending to the energetic limit. By contrast, the D-atom channel exhibits a small peak at low translational energy with a distinctive secondary peak at higher translational energy (approximately 1.8 eV) before falling off to higher energy. In both cases, most of the available energy flows into internal excitation of the water products. Similar distributions are obtained upon reanalysis of D- and H- atom Doppler profiles, respectively, from reactive quenching of OH A (2)Sigma(+) by D-2. The sum of the translational energy distributions for H- and D- atom channels is remarkably similar to that obtained for OH A (2)Sigma(+) + H-2, where the two channels cannot be distinguished from one another. The product translational energy distributions from reactive quenching are compared with those obtained from a previous experiment performed at higher collision energy, quasiclassical trajectory calculations of the post-quenching dynamics, and a statistical model. (C) 2011 American Institute of Physics. [doi: 10.1063/1.3644763

Picking, handling and exhibiting fruit

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Inverse design and implementation of a wavelength demultiplexing grating coupler

Nanophotonics has emerged as a powerful tool for manipulating light on chips. Almost all of today's devices, however, have been designed using slow and ineffective brute-force search methods, leading in many cases to limited device performance. In this article, we provide a complete demonstration of our recently proposed inverse design technique, wherein the user specifies design constraints in the form of target fields rather than a dielectric constant profile, and in particular we use this method to demonstrate a new demultiplexing grating. The novel grating, which has not been developed using conventional techniques, accepts a vertical-incident Gaussian beam from a free-space and separates O-band $(1300\mathrm{nm})$ and C-band $(1550\mathrm{nm})$ light into separate waveguides. This inverse design concept is simple and extendable to a broad class of highly compact devices including frequency splitters, mode converters, and spatial mode multiplexers.Comment: 17 pages, 4 figures, 1 table. A supplementary section describing the inverse-design algorithm in detail has been added, in addition to minor corrections and updated reference

Use of nonintrusive sensor-based information and communication technology for real-world evidence for clinical trials in dementia

Cognitive function is an important end point of treatments in dementia clinical trials. Measuring cognitive function by standardized tests, however, is biased toward highly constrained environments (such as hospitals) in selected samples. Patient-powered real-world evidence using information and communication technology devices, including environmental and wearable sensors, may help to overcome these limitations. This position paper describes current and novel information and communication technology devices and algorithms to monitor behavior and function in people with prodromal and manifest stages of dementia continuously, and discusses clinical, technological, ethical, regulatory, and user-centered requirements for collecting real-world evidence in future randomized controlled trials. Challenges of data safety, quality, and privacy and regulatory requirements need to be addressed by future smart sensor technologies. When these requirements are satisfied, these technologies will provide access to truly user relevant outcomes and broader cohorts of participants than currently sampled in clinical trials

Growth, Condition, and Trophic Relations of Stocked Trout in Southern Appalachian Mountain Streams

Stream trout fisheries are among the most popular and valuable in the United States, but many are dependent on hatcheries to sustain fishing and harvest. Thus, understanding the ecology of hatchery‐reared trout stocked in natural environments is fundamental to management. We evaluated the growth, condition, and trophic relations of Brook Trout Salvelinus fontinalis, Brown Trout Salmo trutta, and Rainbow Trout Oncorhynchus mykiss that were stocked in southern Appalachian Mountain streams in western North Carolina. Stocked and wild (naturalized) trout were sampled over time (monthly; September 2012–June 2013) to compare condition and diet composition and to evaluate temporal dynamics of trophic position with stable isotope analysis. Relative weights (Wr) of stocked trout were inversely associated with their stream residence time but were consistently higher than those of wild trout. Weight loss of harvested stocked trout was similar among species and sizes, but fish stocked earlier lost more weight. Overall, 40% of 141 stomachs from stocked trout were empty compared to 15% of wild trout stomachs (N = 26). We identified a much higher rate of piscivory in wild trout (18 times that of stocked trout), and wild trout were 4.3 times more likely to consume gastropods relative to stocked trout. Hatchery‐reared trout were isotopically similar to co‐occurring wild fish for both δ13C and δ15N values but were less variable than wild trout. Differences in sulfur isotope ratios (δ34S) between wild and hatchery‐reared trout indicated that the diets of wild fish were enriched in δ34S relative to the diets of hatchery‐reared fish. Although hatcheryreared trout consumed prey items similar to those of wild fish, differences in consumption or behavior (e.g., reduced feeding) may have resulted in lower condition and negative growth. These findings provide critical insight on the trophic dynamics of stocked trout and may assist in developing and enhancing stream trout fisheries

Consent Theory as a Possible Cure for Unconscionable Terms in Student-Athlete Contracts

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Ostracode Mg/Ca paleothermometry in the North Atlantic and Arctic oceans: Evaluation of a carbonate ion effect

The reconstruction of deep-sea bottom water temperature (BWT) is important to assess the ocean's response to and role in orbital- and millennial-scale climate change. Deep-sea paleothermometry employs magnesium to calcium (Mg/Ca) ratios in calcitic benthic microfaunas (foraminifera, ostracodes) as a primary proxy method. Mg/Ca paleothermometry may, however, be complicated by bottom water carbonate ion chemistry, which might affect Mg/Ca ratios in shells. To address temperature and carbonate ion influence on Mg/Ca ratios, we studied Mg/Ca ratios in the benthic ostracode genus Krithe in the North Atlantic and Arctic oceans using a 686-specimen core top collection, including 412 previously unpublished analyses. Mg/Ca ratios are positively correlated to temperature in multiple species from the North Atlantic [BWT = (0.885 × Mg/Ca) − 5.69, r2 = 0.73] and for K. glacialis in the Arctic Ocean and Nordic Seas [BWT = (0.439 × Mg/Ca) − 5.14, r2 = 0.50], consistent with previously published calibrations. We found no evidence for a relationship between Krithe Mg/Ca and carbonate ion saturation in the North Atlantic Ocean, Nordic Seas, and Arctic Ocean, supporting the use of Krithe Mg/Ca for reconstructing past BWT

Improved green-light-emitting pyrotechnic formulations based on tris(2,2,2-trinitroethyl)borate and boron carbide

Green-light-emitting pyrotechnic compositions based on tris(2,2,2-trinitroethyl)borate (TNEB) and boron carbide have been investigated. The best performing formulations were found to be insensitive to various ignition stimuli, and exhibited very high spectral purities and luminosities compared to previously reported green-light-emitting formulations